作　　者： (陈慧兰）; (王志林）; ; (唐雯霞）;

机构地区： 南京大学

出　　处： 《高等学校化学学报》 1992年第8期1026-1029,共4页

摘　　要： 运用光度法研究了RCo(Salen)L配合物在甲醇中热分解反应动力学;测定了Co—C键断裂的速率常数及活化能,得到表观速率常数顺序为i-C3H7>i-C4H9>n-C4H9>n-C3H7>C2H5,活化能顺序为i-C3H7 The kinetics of thermolysis of RCo(Salen)L complexes in methanol was studied by using UV-Vis spectrophotometry.The observable rate constants and the energy of activation were determined.The sequence of the rate constants is i-C3H7>i-C4H3>n-C4H9>n-C3H7>C2H5 and of the energy of activation is i-C3H7

关 键 词： 辅酶 热分解 烷基钴西佛碱

领　　域： [理学—无机化学] [理学—化学]