作　　者： ; ; ; ; ; ;

机构地区： 西北师范大学化学化工学院

出　　处： 《光谱学与光谱分析》 2004年第4期402-406,共5页

摘　　要： 对比研究了非离子表面活性剂聚氧乙烯辛基酚醚 (OPE 10 ,n =10 )及聚氧乙烯特辛基酚醚 (TritonX 10 0 ,n =10 )和 β 环糊精 (β CD)协同诱导 1 溴萘 (1 BrN)室温磷光光谱。根据分子大小和 β CD空腔尺寸分析阐述了 β CD与非离子表面活性剂形成 1∶1二元包络物 ,OPE 10和TritonX 10 0分子内的辛基和苯基团被包络在空腔内 ,驱除了空腔内的水分子 ,使空腔内微环境的极性更低 ,通过更强的疏水相互作用进一步和 1 BrN形成了结构紧密的稳定 1∶1∶1三元包络物。β CD/OPE 10 / 1 BrN和 β CD/TritonX 10 0 / 1 BrN包络物的表观稳定常数分别为 1 0 9× 10 5和 4 4 7× 10 5L2 ·mol- 2 。在 β CD空腔内 ,1 BrN的重原子对OPE 10和TritonX 10 0的荧光产生猝灭作用。对于更稳定的 β CD/TritonX 10 0 / 1 BrN三元体系 ,特辛基可更好地屏蔽溶液中的溶解氧和碘离子的猝灭作用 ,观察到了TritonX 10 0分子内苯基和受体 1 BrN之间的能量转移。 Room-temperature phosphorescence of 1-BrN induced by a combination of OPE-10 and Triton X-100 with β-CD was comparatively studied. In terms of molecular size and dimensions of β-CD, the octyl group and phenyl group of OPE-10 and Triton X-100 were incorporated into the cavity of β-CD and the complexes with the stoichiometry of 1∶1 were formed. The removal of water molecules inside the cavity results in a greater apolar interior. By enhanced hydrophobic interaction, the cavity occupied by OPE-10 and Triton X-100 is able to further capture another 1-BrN and form close packing 1∶1∶1 ternary inclusion complexes with apparent stability constant of 1.09×10 5 and 4.47×10 5 L 2·mol -2, respectively. 1-BrN shows bright phosphorescence at room temperature due to the greater rigidity in the limited space and the favorable microenvironment shielding from external quenchers and quenching effect on the fluorescence of the phenyl group of OPE-10 and Triton X-100 within the same cavity. In the case of Triton X-100, the larger tert-octyl group better shields off external quenchers such as dissolved oxygen and iodide ion. Energy transfer from the excited phenyl group of Triton X-100 to adjacent 1-BrN acceptor was observed.

关 键 词： 非离子表面活性剂 环糊精 溴萘室温磷光 包络物 刚性 荧光分光光度计

领　　域： [化学工程] [理学] [理学]