作　　者： ; ; ; ; ;

机构地区： 河南大学化学化工学院

出　　处： 《化学研究》 2003年第2期55-58,共4页

摘　　要： 在HAc NaAc缓冲溶液中,玻碳电极上修饰的少量碳纳米管对腺嘌呤的氧化起增强作用.研究了腺嘌呤在修饰电极上的伏安行为,优化了电氧化的最佳条件,并对其进行含量测定.方法的线性范围为2.0×10-8～1.0×10-5mol/L,检出限为1.0×10-9mol/L.用于模拟样品中痕量腺嘌呤的测定,结果满意. In the solution of HAcNaAc, trace carbon nanotube modified on the electrode greatly increases the anodic peak current of adenine. The electrochemical behavior of adenine was studied and the determination conditions were optimized. The results showed that stripping peak current is proportional to the concentration over the range 2.0×108～2.0×10-5 mol/L with 30 seconds accumulation. The detection limit is 1.0×10-9 mol/L. The method has been successfully applied to the determination of adenine in simulated samples.

关 键 词： 碳纳米管 修饰电极 阳极 溶出伏安法 测定 腺嘌呤 电化学

领　　域： [理学] [理学]