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Mg^(2+),Li^+//SO_4^(2-)-C_2H_5OH-H_2O体系在25℃的等温互溶度和相关系
Isothermal Mutual Solubility and Phase Relation of Mg^(2+),Li^+//SO_4^(2-)-C_2H_5OH-H_2O System at 25 ℃

作  者: ; ; (等);

机构地区: 兰州大学化学化工学院

出  处: 《应用化学》 2003年第2期175-177,共3页

摘  要: The isothermal mutual solubility and phase relation of MgSO 4-Li 2SO 4-C 2H 5OH-H 2O system at 25 ℃ have been investigated by using a homemade micro-equilibrium and sampling apparatus. The demixing phenomenon of the system′s at below room temperature was observed. The precise demixing composition and composition of double-saturated point of the system have been determined. A unique effect, namely additive property between MgSO 4 and Li 2SO 4 has been observed and explained in terms of "pseudo-ternary system" concept. An empirical formula has been worked out to correlate the mutual solubility. The isothermal mutual solubility and phase relation of MgSO 4-Li 2SO 4-C 2H 5OH-H 2O system at 25 ℃ have been investigated by using a homemade micro-equilibrium and sampling apparatus. The demixing phenomenon of the system′s at below room temperature was observed. The precise demixing composition and composition of double-saturated point of the system have been determined. A unique effect, namely additive property between MgSO 4 and Li 2SO 4 has been observed and explained in terms of 'pseudo-ternary system' concept. An empirical formula has been worked out to correlate the mutual solubility.

关 键 词: 硫酸镁 硫酸锂 乙醇 互溶度 相关系 三元体系 相平衡 无机水盐体系

领  域: [理学] [理学]

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