作　　者： ; ; ; ; ; ;

机构地区： 广西师范大学化学化工学院化学化工系

出　　处： 《合成化学》 2002年第5期464-467,共4页

摘　　要： 以酒石酸为原料 ,经成环制酸、酯化、肼解、与芳香醛缩合 ,制备了 7个 4 ,5 -咪唑双酰腙 ,并用元素分析 ,IR,1H NMR,13 C NMR对它们的结构进行了表征。实验结果表明 ,酰肼与芳香醛在冰醋酸中进行缩合酰腙化一步 ,具有反应快速、产率高、条件温和。 Imidazole-4,5-dicarboxylic acid, which was got from tartaric acid by cyclization, was esterified, hydrazinnolized and then condensated with aroyladehydes in glacial acetic acid to synthesize seven new imidazole-4,5-diacylhydrazones in mild condition with high yield, especially the condensation reaction was finished very quickly(from several seconds to several minutes) and the work-up was simple too. These new compounds were characterized by elementary analysis, IR, 1H NMR and 13C NMR.

关 键 词： 咪唑双酰腙 合成 表征 缩合 酒石酸 酰肼 芳香醛

领　　域： [理学] [理学]