机构地区: 中国科学技术大学物理学院物理系
出 处: 《物理学报》 1991年第8期1339-1343,共5页
摘 要: 对(Bi,Pb)_2Sr_2Ca_2Cu_3O_y单相样品进行不同条件下的热处理,通过X射线衍射、电阻-温度关系、交流磁化率,以及Hall系数等测量,发现样品均具有较好的单相性,随着热处理条件的变化,其超导转变中点温度(T_c)有规律地分布在100—110K之间,T_c随载流子浓度(n_H)的增加而升高。实验结果表明,热处理条件对样品的相结构、超导转变温度和载流子浓度均有很大影响。作者认为,Bi系2223相的T_c,n_H与热处理所导致的氧含量变化以及局域组成和结构完整性之间存在着重要的关联。 Single phase (Bi, Pb)2 Sr2Ca2Cu3O_y samples have been prepared with different heat treatments. X-ray diffraction, the dependence of resistance on temperature, ac. susceptibility and Hall coefficient have been investigated. We find that all samples are of 2223 single phase, the midpoint superconducting transition temperatures (Tc) are above 100K, and Tc increases mo-notonically with the carrier concentration (nH)- The experimental results show that the conditions of heat treatment affect the phase structure, Tc and nH for the Bisystem. We propose that Tc and n_H. of the Bi-system are closely related to oxygen content, local composition and structure perfection.