机构地区: 大连轻工业学院化学工程系
出 处: 《有机化学》 2001年第8期603-605,共3页
摘 要: 首次合成出中位-四-(对十六酰氧基苯基)卟啉(TPPPH2)及其锌配合物(简称'PPZn),研究了其液晶性质,结果表明这种卟啉及其锌配合物具有液晶性质. The meso-tetra-(4-palmitoyloxyphenyl)porphyrin(TPPPH2) and zinc complex(TPPPZn) were synthesized and characterized by means of molar conduction, elemental analysis, and UV-visible, infrared photoacoustic as well as H-1 NMR spectroscopy. The physical behavior of TPPPH2 and TPPPZn was determined by differential scanning calorimetric(DSC). The results show that TPPPZn exhibit liquid crystal behaviors.