作　　者： ; ; ; ; ; ;

机构地区： 吉林大学化学学院

出　　处： 《高等学校化学学报》 1991年第12期1640-1643,共4页

摘　　要： 用INDO/CI法研究了[M_2(η~5-C_5H_5)_2(CO)_4]及M(η~5-C_5H_5)(CO)_2Cl(M=Fe,Ru)体系的电子光谱,讨论了谱带的跃迁机理、电荷转移性质及同一标号谱带的蓝移现象,并对[MC_p(CO)_2]_2体系的异构化反应性及光化学反应的可能机理进行了探讨。 The Electronic Spectra of CMCP(CO)2]2 and MCp(CO)2Cl(M = Fe,Ru) are studied by means of INDO/CI method. The calculated values of wave number and transition intensity of the spectra correspond with the experimental results. The bands are assiged and the nature of their charge trasfer is discussed. The blue shift of the same label band with M-Fe,Ru are explained. In addition, the reactions of isomerization and photochemistry are discussed.

关 键 词： 法 铁 钌 簇合物 电子光谱

领　　域： [理学] [理学]