作　　者： ; ; ; ;

机构地区： 东北大学材料与治金学院材料各向异性与织构工程教育部重点实验室

出　　处： 《Transactions of Nonferrous Metals Society of China》 2011年第10期2270-2275,共6页

摘　　要： 用CALPHAD方法评估了Co-Cr-W三元系,计算了1000,1200和1350℃的相平衡。采用亚正规溶体模型描述了液相,fcc相,bcc相和hcp相。σ相,μ相,R相分别用模型(Co,W)8(Cr,W)4(Co,Cr,W)18,(Co,Cr,W)7W2(Co,Cr,W)4和(Co,W)27(Cr,W)14(Co,Cr,W)12来表示;得到了自洽的热力学相互作用参数。计算的1000,1200和1350℃的相图与实验数据吻合。 The Co-Cr-W ternary system was critically assessed using the CALPHAD technique.The solution phases including the liquid,γ-Co,ε-Co and α-Cr were described by a substitutional solution model.The σ,μ and R phases were described by three-sublattice models of（Co,W）8（Cr,W）4（Co,Cr,W）18,（Co,Cr,W）7W2（Co,Cr,W）4 and（Co,W）27（Cr,W）14（Co,Cr,W）12,respectively,in order to reproduce their homogeneity ranges.A self-consistent set of thermodynamic parameters for each phase was derived.The calculated isothermal sections at 1 000,1 200 and 1 350 ℃ are in good agreement with the experimental data.A eutectoid reaction of R μ＋γ-Co＋σ in this ternary system was predicted to occur at 1 022 ℃.

关 键 词： 三元系 基高温合金 相图 热力学 相 相 相

领　　域： [金属学及工艺] [一般工业技术] [金属学及工艺]