作　　者： ; ; ; ; ; ; ; ; ; ;

机构地区： 暨南大学生命科学技术学院纳米化学研究所

出　　处： 《无机化学学报》 2011年第4期764-770,共7页

摘　　要： 本文通过溶剂热法"一锅"制备了镍掺杂的花状纳米碳片(Ni/FCNAs)。借助X射线衍射仪(XRD)、扫描电子显微镜(SEM)和透射电子显微镜(TEM)对该复合材料的表面形貌和结构进行了分析。循环伏安和恒流充/放电测试结果表明,Ni/FCNAs具有较大的比电容值且电化学稳定性良好。在电流密度为0.1 A.g-1时,Ni/FCNAs电极的比电容可达176 F.g-1。本文同时也提出了Ni/FCNAs可能的形成机理。 Ni-doped flower-like carbon nanosheet aggregations（Ni/FCNAs） were synthesized via a one-pot solvothermal method followed by a subsequent calcination process at 900 ℃ in nitrogen atmosphere.The surface morphologies and structures of composites were examined by scanning electron microscope（SEM）,transmission electron microscope（TEM） and X-ray diffraction（XRD）.Cyclic voltammetry and galvanostatic charge/discharge experiments were adopted to investigate their electrochemical behaviors.The results show that the doped nickel particles could enhance both specific capacitance and electrochemical stability.The Ni/FCNAs show large specific capacitance up to 176 F·g-1 with the current density of 0.1 A·g-1.The possible formation mechanism of Ni/FCNAs has also been proposed on the basis of experimental results.

关 键 词： 镍掺杂 纳米碳片 溶剂热 超级电容器

领　　域： [一般工业技术] [一般工业技术]