作　　者： ; ; ;

机构地区： 吉林大学化学学院无机合成与制备化学国家重点实验室

出　　处： 《高等学校化学学报》 2011年第3期678-682,共5页

摘　　要： 采用微波辅助溶剂热法合成了烟酸锌配位聚合物,并对其性质进行了表征.讨论了时间、温度、底物浓度、加热方法及溶剂等因素对产物的结晶情况和生长过程中粒径大小的影响.通过结合微波溶剂热与传统溶剂热两种方法,既使合成反应具备了微波加热反应速度快的优点,同时又使晶体成核均匀,利用该法合成获得了适于晶体结构解析的单晶体. Bis（nicotinate）zinc was successfully synthesized in 10 min under microwave-assisted solvothermal condition,the influences of reaction time,temperature,solvent,substrate concentration and heating method on the crystallization of the complexes were disscussed.Microwave heating not only shorten the reaction time significantly and improve the yield and purity of product,but also has good reproducibility and stability of the amplification.The combination of the microwave-assisted solvothermal method and the conventional solvothermal method not only has the advantages of microwave heating,but also can obtain crystals with large particle size that suitable for structural analysis.

关 键 词： 微波 溶剂热 烟酸锌 晶体

领　　域： [理学] [理学]