作　　者： ; ; ; ; ; ; ;

机构地区： 杭州师范大学材料与化学化工学院有机硅化学及材料技术教育部重点实验室

出　　处： 《有机化学》 2009年第12期1899-1905,共7页

摘　　要： 过渡金属膦配合物在有机合成和催化反应中的应用非常广泛,大量含膦杂原子配体被设计合成,利用其特定的配位能力,和过渡金属配位成过渡金属膦配合物,并测试其对特定有机化学反应的催化性能.硅氢加成反应是有机硅化学中的重要反应,多种过渡金属包括铂、钯、铑、钌等的膦配合物对于硅氢加成反应均有催化活性.综述了近几年来过渡金属膦配合物在硅氢加成反应中的应用进展. Transition metal-phosphorus complexes are very important for the organic synthesis and catalytic reactions. Many phosphorus ligands and heteroatom ligands containing phosphorus were synthesized. On the other hand, hydrosilylation is one of the most important reactions in organosilicon chemistry, and many organosilicon monomers containing functional groups have been synthesized via this reaction. The catalytic hydrosilylation process is well established, and many transition metals such as platinum, palladium, rhodium, ruthenium or other transition metal phosphorus complexes are widely used in hydrosilylation reactions, though it is still desirable to further increase the catalytic activity and selectivity and to minimize the amount of catalyst. In this paper, the progress of transition metal-phosphorus complexes in hydrosilylation during recent years is reviewed.

关 键 词： 膦配合物 硅氢化反应 过渡金属

领　　域： [理学] [理学] [理学] [理学]