机构地区: 衡阳师范学院化学与材料科学系
出 处: 《环境工程学报》 2009年第11期1961-1964,共4页
摘 要: 利用废弃蛋壳为原料、尿素为添加剂,合成纳米碳羟基磷灰石(CHAP)用于吸附水中双酚A(BPA)。利用红外光谱、扫描电镜和X射线能谱测试技术对CHAP样品表面化学进行了表征,同时考察了环境因子pH值、吸附时间和BPA初始浓度对吸附的影响。实验结果表明,CHAP对BPA去除率在酸性(pH=3~6)溶液中较好,而在中性和碱性环境中减弱。通过静态吸附实验数据计算分析得知,CHAP对BPA吸附符合Langmuir和Freundlich等温式,准二级动力学模型比准一级动力学模型能更好地描述CHAP对BPA吸附动力学行为。 The adsorption of biphenol-A(BPA) from aqueous solution by home-made carbonate hydroxylapatite(CHAP) synthesized by using abandoned eggshell and urea was characterized by FT-IR,SEM and EDS.Factors that might influence the adsorption performance were investigated,such as pH values,adsorption period,biphenol-A initial concentration from aqueous solution.The results showed that absorption of biphenol-A on the CHAP was better pH=3-6 than pH〉6 from aqueous solution.The equilibrium sorption datas could be described by the Langmuir and Freundlich isotherm models.The second-order kinetic model provided the best correlation of the used experimental data compared to the first-order kinetic model.