机构地区: 南昌大学
出 处: 《物理化学学报》 1998年第10期957-960,共4页
摘 要: The crystal structure and infrared absorption spectra of nanocrystallineDy1-xSrxCoO3-y (0.0≤x≤1.0) were studied. The results show that the latttice paratmeters werehigger than microcrystallines. The mixed oxides crystallized in orthorhombic (0.0≤x≤0.5) ortetragonal system (0.6≤x≤0.9) or hexagonal system (x=1.0 ). With symmetry centre of crystalstructure variation, the spectra bands of nanocrystallines were fissioned. The infrarea absorptionspectra of nanocrystallines appeared as quantum size effect. The crystal structure and infrared absorption spectra of nanocrystallineDy1-xSrxCoO3-y (0.0≤x≤1.0) were studied. The results show that the latttice paratmeters werehigger than microcrystallines. The mixed oxides crystallized in orthorhombic (0.0≤x≤0.5) ortetragonal system (0.6≤x≤0.9) or hexagonal system (x=1.0 ). With symmetry centre of crystalstructure variation, the spectra bands of nanocrystallines were fissioned. The infrarea absorptionspectra of nanocrystallines appeared as quantum size effect.