机构地区: 中山大学化学与化学工程学院化学系
出 处: 《中国稀土学报》 1998年第3期284-287,共4页
摘 要: 用微波辐射法合成了(Ce0.67Tb0.33)MgAl11O19(PG)和BaMgAl10O17(PB)两种荧光体,经X射线粉末衍射分析,其d值和I/I0值与JCPDF3673和26163基本一致。计算得到PG的晶胞参数a=05582nm,c=21884nm;P-B的晶胞参数α=05616nm,c=22614nm。测定了两种荧光体的激发光谱和发射光谱。P-G的色坐标x=0316,y=0565;P-B的色坐标x=0156,y=0106。与市售同类荧光粉相比,P-G的相对发光强度为88%,P-B的相对发光强度为80%。 The phosphors(Ce 0 67 Tb 0 33 )MgAl 11 O 19 (P G) and BaMgAl 10 O 17 ∶Eu 2+ (P B) were synthesized using the microwave irradiation technique. The data of X ray powder diffraction( d values and I/I 0 values) are basically coincided with the data of JCPDF 36 73 and 26 163 cards. The calculated cell dimensions are a =0 5582 nm, c =2 1884 nm for P G, and a =0 5616 nm, c =2 2614 nm for P B. The excitation spectrum and the emission spectrum of the phosphors were measured. The chromatic coordinates are x =0 316, y =0 565 for P G, and x =0 156, y =0 106 for P B. The relative luminescent intensity is about 88%(P G) and 80%(P B) respectively compared with the same commercial phosphors. The pictures of SEM of the phosphors were also detected.