作　　者： ; ; ; ; ;

机构地区： 青岛科技大学化工学院

出　　处： 《催化学报》 2009年第5期401-406,共6页

摘　　要： 合成、表征了新型BrΦnsted-Lewis酸性离子液体1-(3-磺酸)-丙基-3-甲基咪唑氯锌酸盐([HO3S-(CH2)3-mim]Cl-ZnCl2),并将其用于催化松香二聚反应.结果表明,[HO3S-(CH2)3-mim]Cl-ZnCl2(ZnCl2摩尔分数x>0.5)为BrΦnsted和Lewis双酸性,且以[HO3S-(CH2)3-mim]Cl-ZnCl2(x=0.64)的催化性能较佳.在松香5.0g,甲苯15g,离子液体质量分数5%,反应温度110oC和反应时间4h的较佳实验条件下,所得产物聚合松香的软化点为118oC.此外,该催化剂的使用有利于产物的分离且分离的离子液体催化剂具有良好的重复使用性能. Brφnsted-Lewis acidic ionic liquids 1-（3-sulfonic acid）-propyl-3-methylimidazole chlorozincinates （[HO3S-（CH2）3-mim]Cl- ZnCl2） were synthesized and characterized. The characterization results indicated that [HO3S-（CH2）3-mim]Cl-ZnCl2 （molar fraction of ZnCl2 x 〉 0.5） had both BrCnsted and Lewis acid properties. The catalytic properties of these ionic liquids were investigated using the dimerization of rosin, and it was shown that ionic liquid [HO3S-（CH2）3-mim]Cl-ZnCl2 （x = 0.64） was a good catalyst. Under the optimum conditions for polymerization, i.e., rosin 5.0 g, toluene 15 g, the mass fraction of ionic liquid 5%, reaction temperature 110 ℃, and reaction time 4 h, a product with the softening point of 118 ℃ was obtained. It was also found that the product was easily separated from the reaction mixture and the ionic liquid catalyst had good reusability.

关 键 词： 酸性离子液体 松香 二聚反应 催化

领　　域： [理学] [理学]