机构地区: 深圳大学化学与化工学院
出 处: 《中国西部科技》 2009年第6期6-7,共2页
摘 要: 以钼酸钠为钼源,乙二胺为有机配体通过水热法合成了一种几何外形为长方体的紫红色晶体(C2H8N2)11[Na2Mo10P6O60],并利用XRD、SEM和DSC等分析测试手段对晶体的结构、形貌和性能进行了表征。实验表明最佳原料配比(摩尔比)为钼酸钠:磷酸:乙二胺:水=(0.41~1.00):(1.65~3.31):(0.063~4.07):111。 Molybdenum inorganic-organic hybrids (C2H8N2)11[Na2Mo10P6O60] were synthesized using sodium molybdate as the inorganic main body, the ethylene diamine as organic legend in hydrothermal system. The structure and properties were characterized by XRD, SEM and DSC techniques. The optimum ratio of raw material is nNaMo4.2H2O: nH3PO4: nEn: nH2O= (0.41-1.00) : (1.65-3.31) : (0.063-4.07) : 111.