机构地区: 遵义医学院珠海校区生物工程系
出 处: 《广东化工》 2009年第1期28-30,103,共4页
摘 要: 合成了N,N’-二(3-硝基亚水杨基)-2,6-吡啶二氨席夫碱及其Cu(Ⅱ),Ni(Ⅱ),Zn(Ⅱ),Mn(Ⅱ)的配合物,用元素分析、IR、摩尔电导和电子光谱对所得化合物进行了表征,对席夫碱配体进行了1H NMR和MS表征,给出了化合物可能的空间结构。 The symmetrical schiff base N,N -bis(3-nitrosalicylidene)-2,6-pyridinediamine and its Cu( Ⅱ ), Zn( Ⅱ ), Ni( Ⅱ ), Mn( Ⅱ ) complexes were synthesized. The compounds were characterized by elemental analysis, IR, molar conductivity and electronic spectrum. The ligand was further characterized by ^1H NMR and MS. The possible coordination structure of the compounds were also given.