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ATO包覆型导电纤维的制备
Preparation of ATO-Coated Conductive Fiber

作  者: ; ; ; ;

机构地区: 华南理工大学材料科学与工程学院

出  处: 《华南理工大学学报(自然科学版)》 2007年第8期70-74,共5页

摘  要: 以莫来石纤维为基体,采用共沉淀法在其表面沉积一层锑掺杂氧化锡(ATO),制得导电纤维,并研究了制备工艺对导电纤维电阻率和颜色的影响.结果表明:热处理温度为600~1 000℃时制备的导电纤维的电阻率低于50Ω.cm,与同条件下制备的ATO的电阻率相差不大;热处理温度为1 000℃以上时,由于莫来石纤维中的部分A l3+进入氧化锡晶格出现补偿效应,致使导电纤维的电阻率急剧下降;导电纤维的亮度L*大于同温度下制备的ATO的亮度,而且差值都在10个单位以上;导电纤维与硫酸钡标准样品的色差ΔE小于10个NBS. Conductive fiber was prepared by coating a layer of antimony-doped tin dioxide (ATO) on the surface of mullite fiber via the co-precipitation method. The influence of the preparation process on the electric resistivity and the color of the prepared conductive fiber was then investigated. The results show that ( 1 ) after heat treatment at 600 to 1000℃ , the conductive fiber is of a resistivity less than 50 Ω·cm, which is almost the same as that of the ATO prepared in the same conditions; (2) when the heating temperature is higher than 1000 ℃, the resistivity of the conductive fiber abruptly decreases due to the compensative effect resulting from the entry of a part of Al^3+ into the SnO2 lattice ; (3) the lightness L* of the conductive fiber is higher than that of the ATO prepared at the same temperature, with a difference being more than 10 units; and (4) the chromatic aberration AE between the conductive fiber and the standard barium sulfate sample is less than 10 NBS.

关 键 词: 锑掺杂氧化锡 导电纤维 制备 包覆 颜色

领  域: [一般工业技术]

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