作　　者： ; ; ;

机构地区： 华东交通大学基础科学学院化学化工系

出　　处： 《化学研究与应用》 2007年第9期1028-1032,共5页

摘　　要： Nanosized rare earth solid superacid SO42/TiO2-Nd2O3 was prepared and was used as a catalyst for cyclohexand dehydration to form cyclohexene.The influence of various preparation parameters such as the concentration of Nd3+,the concentration of H2SO4 and the calcination temperature on the catalytic activity was studied.It indicates that SO42-/TiO2-Nd2O3 has fairly high catalytic activity on the dehydration of cyclohexand and the yield of cyclohexene can reach 79.73%.The SO42-/TiO2-Nd2O3 catalytic mechanism for cyclohexand dehydration and the Nd3+ effect on the catalytic activity was also disccused. Nanosized rare earth solid superacid SO42/TiO2-Nd2O3 was prepared and was used as a catalyst for cyclohexand dehydration to form cyclohexene.The influence of various preparation parameters such as the concentration of Nd^3＋,the concentration of H2SO4 and the calcination temperature on the catalytic activity was studied.It indicates that SO4^2-/TiO2-Nd2O3 has fairly high catalytic activity on the dehydration of cyclohexand and the yield of cyclohexene can reach 79.73%.The SO4^2-/TiO2-Nd2O3 catalytic mechanism for cyclohexand dehydration and the Nd^3＋ effect on the catalytic activity was also disccused.

关 键 词： 稀土固体超强酸 环己烯 环己醇 合成

领　　域： [理学] [理学]