机构地区: 武汉化工学院化工与制药学院化学工程与工艺系
出 处: 《应用化学》 1996年第6期72-74,共3页
摘 要: 钴铬复合氧化物超细微粒的制备、结构及其催化性能刘常坤,申永存,奚强(武汉化工学院精细化工系武汉430073)关键词钴铬复合氧化物,超细微粒,催化剂,制备,结构,催化氧化,三甲苯酚,三甲苯醌2,3,6-三甲苯酚(TMP)的氧化产物之一2,3,6-三甲苯... Cobalt chromium mixed oxide ultrafine particle catalysts were prepared by coprecipitation and sol-gel methods. The catalytic properties of catalysts for catalytic oxidation of 2,3,6-trimethylphenol to trimethyl-p-benzoquinone were investigated.It is shown that the catalyst with Co/Cr=1 prepared by sol-gel method is the best.The structures of catalysts were characterized by TEM,XRD and DTA-TG.The mixed oxide is amorphous under 350℃.The thermal stability of this amorphous catalyst is higher than that of Co3O4 and Cr2O3.