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Fe^(3+)-H_2O_2-Rh6G化学发光体系测定水中的邻苯二酚
Fe^(3+)-H_2O_2-Rh6G chemiluminescence system for the determination of catechol in water

作  者: ; ; ;

机构地区: 涪陵师范学院化学系

出  处: 《化学研究与应用》 2006年第1期107-109,共3页

摘  要: A novel chemiluminescence system for the determination of catechol in water was first described in this paper.It was based on the chemiluminescence reaction of catechol and hydroxyl radical that was the product of the reaction of Fe3+and H2O2.Rh6G could enhance the chemiluminescence intensity.The linear range was 10-2000μg/L with a detection limit of 5μg/L(3σ).The relative standard deviation was 3.1% for 200μg/L of catechol(n=11).The proposed method was successfully applied to the determination of catechol in water. A novel chemiluminescence system for the determination of catechol in water was first described in this paper. It was based on the chemiluminescence reaction of catechol and hydroxyl radical that was the product of the reaction of Fe^3 + and H2O2. Rh6G could enhance the chemiluminescence intensity. The linear range was 10 -2000μg/L with a detection limit of 5μg/L(3σ). The relative standard deviation was 3.1% for 200μg/L of eatechol( n = 11 ). The proposed method was successfully applied to the determination of catechol in water.

关 键 词: 羟基自由基 罗丹明 邻苯二酚 流动注射 化学发光

领  域: [理学] [理学]

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