机构地区: 韶关学院化学与环境工程学院化学系
出 处: 《韶关学院学报》 2005年第6期70-72,110,共4页
摘 要: 在稀醋酸溶液中,微波辐射下壳聚糖与Zn2+反应制备了壳聚糖Zn2+配合物,然后将制得的配合物与环氧氯丙烷在微波辐射下进行交联反应后,用稀酸除去Zn2+,合成了具有Zn2+孔穴的交联壳聚糖树脂.实验考察了该树脂对一些金属离子的吸附性能,并对影响树脂吸附性能的因素进行了研究. A cross - linked chitosan resin Zn( Ⅱ )cavity have been synthesized by forming chitosan coordination of Zn^2+ ions as template in dilute acetic acid solution under microwave irradiation, and then by reacting the Zn^2+ - chitosan complexes with Epoxychoropropane as crosslinking agent under microwave irradiation, and removing off Zn^2+ ions with dilute acid . The adsorption capaciry for Zn^2+ , Cu^2+ , Ni^2+ and Co^2+ , the influences on the adsorption capacity have also been investigated.
领 域: [文化科学]