机构地区: 浙江大学化学系
出 处: 《Chinese Journal of Chemical Physics》 1995年第4期340-346,共7页
摘 要: 本文考价HCl从H_2O到DMSO(20wt%)-EtOH-H_2O中的迁移热力学性质,分析讨论了离子的溶剂化作用、溶质-溶剂相互作用及溶液的微观结构,并应用修正的Born方程对实验结果进行了解释。本文的工作为DMSO在临床试验及工业生产中的广泛应用提供了重要的参考数据和信息。 Abstract In this paper the transfer thermodynamic properties of HCl from H_2O to DMSO(20wt% )-EtOHH_2O were explored and discussed.The ionic solvation,solute-solvent interaction and micro-structrue of the solution were analysed,and the results were accounted for in terms of the revised Born equation.Thus the data and relevant information are important and significant for the application of DMSO to the relevant industries.