机构地区: 白城师范学院化学系
出 处: 《分子科学学报》 2005年第3期48-51,共4页
摘 要: 研究了(Z)1[2(三o甲苯基锡基)乙烯基]环戊醇(1)和(Z)1[2(三o甲苯基锡基)乙烯基]环己醇(2)及其一碘化物(3,4)的结构和1HNMR测定结果,探讨了不同碳环醇和碘取代后对分子O→Sn内配位程度和稳定性的影响. In this paper,the influence of the intermolecular O→Sn and the molecular stability has been studied according to result from crystal structure and^(1)HNMR of ((Z)-1-[2-(tri-o-tolylstannyl))vinyl]-1-cyclopentanol,(Z)-1-[2-(tri-o-tolylstannyl)vinyl]-1-cyclohexanol and their di-o-tolyliodostannyl derivative,the changing regularities of ^(1)H-NMR has been investigated systematically.