机构地区: 哈尔滨工业大学材料科学与工程学院
出 处: 《中国表面工程》 1998年第3期20-26,共7页
摘 要: 使用XRD、SEM和TEM对比研究了激光熔覆和熔铸Ni-Cr-B-Si-C合金的显微组织。结果表明:激光熔覆组织由块状CrB型硼碳化物,正交结构的树枝状Cr7C3型碳化物,胞技状γ-Ni固熔体、共晶产物以及非晶相等组成。俄局部成分条件,形成γ-Ni+M233C6共晶和γ-Ni十镍棚化物共晶。熔夜过程的非平衡性质导致层状γ-Ni+Ni3B稳定凝固和非规则γ-Ni+Ni2B亚稳定凝固并存。熔化炉冷后的熔铸组织粗大,由六方结构的六棱柱状Cr7C3型碳化物、γ-Ni基因港体等轴晶、Ni/Ni3B类层状共晶以及近球形Ni3B化合物组成。前者组织较后者细化约1~2个数量级。 Microstructures of laser cladding and cast Ni-Cr-B-Si-C alloy were investigated by means of XRD,SEM and TEM. The former is 1-2 order finer than the latter. The microstructure of the laser cladding is composed of blocky CrB type chromium carbon borides, orthorhombic Cr,C, type chromium boron carbide dendrites, cellular-dendritic γ-Ni solid solution, various cutectic products and an amorphous phase. Either a eutectic of γ-Ni+M23C6 or a eutectic of γ-Ni+nickle borides can be formd depending on the local comosition.Lamellar γ Ni+Ni3B stable solidification and irregular γ-Ni+Ni2B metastable solidification take place at the same hme because of the rapid Cooling in the laser cladding process. The microstructure of the cast alloy comprises hexagonal Cr7C3 of hex prisms, Y-Ni equiaxial grains, γ-Ni+Ni3B lamellae-like eutectic and near-spherical Ni3B.