机构地区: 广西师范大学化学化工学院化学系
出 处: 《广西师范大学学报(自然科学版)》 1993年第2期54-57,共4页
摘 要: 以亚硫酰氯为试剂和溶剂合成了8个手性α-溴代酸酯,其中两个是新化合物。与传统方法相比,不需使用红磷,反应条件温和、操作简便、产率高且几乎全为α-—溴代产物。 Eight chiral a-bromo-carboxylic esters were synthesized by using thionyl chloride as a solvent and a reagent, two of them are new compounds. Compared with traditional methods, it needn't red phosphorous and easy to operate. The yields were excellent and the products almost were α-monobrominated products.