机构地区: 中国科学院物理研究所磁学国家重点实验室
出 处: 《中国稀土学报》 2005年第4期385-393,共9页
摘 要: 围绕具有一级磁性相变的La-Fe基NaZn13型化合物的磁场诱导熵变研究,从室温磁制冷目的出发讨论了材料研究和熵变机制。La-Fe-Si在190K附近5T磁场下的熵变值可达29J.kg-1.K-1。用少量Co替代Fe,可以获得室温附近5T磁场下熵变为15J.kg-1.K-1的大熵变材料。这类材料中的熵变主要由磁有序熵变和晶格熵变组成。分析了一级磁性相变体系中磁有序熵变和晶格熵变对总熵变的贡献,并发现大的熵变来源于被晶格贡献抵消后的磁有序熵变。 Magnetic field induced entropy change was investigated for La-Fe based NaZn_(13)-type compounds with magnetic first-order phase transition. In view of magnetic refrigeration at room temperature, the developing of the materials and the understanding of the entropy change were reviewed. For La-Fe-Si compounds, the entropy change about 29 J·kg^(-1)·K^(-1) was obtained at 190 K under the magnetic field of 5 T. While a large entropy change of about 15 J·kg^(-1)·K^(-1) near room temperature under 5 T can be obtai...
领 域: [一般工业技术]